GoldenEye

Goldeneye is a golden film, there is no other way to put it.
It could definitely be the best Bond film with Pierce Brosnan in the role, and it is easily up with the best Bond films of all time.
The whole production is expertly crafted, from the opening scene where Bond's partner Alec Trevalyn - 006 (Sean Bean) - is "killed", to the end battle between Bond and Trevalyn.
The song is one of the best, as Tina Turner takes the sound of the franchise all the way up to 11.
The battles, the story development and the metting between Bond and Natalya Simonova (Bond girl Izabella Scorupco) are all done just brilliantly. It's difficult to describe why it's so good - potentially because Licence to Kill was so bad, the six year wait for a Bond film, or Brosnan's style was just that damn brilliant. 
If you haven't seen it, go and see it. The Americanisation of Bond means there seems to be a lot more action than what has been seen in previous films, but the way it is presented makes the transition seamless.
Watch it - it's a must-see.

GoldenEye (1995): 130 minutes
Bond Songs: GoldenEye by Tina Turner